A UK departure should be checked under UK passenger-rights rules. A complex connection may involve more than one legal question, but double recovery should not be assumed.
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What to check
The route and operating carrier matter as much as the number of hours. Check which rule covered the flight on its travel date before using a compensation amount.
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What to do next
Read the applicable country rule first, then send the airline the facts that support that specific claim.
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Official sources
- UK Department for Transport: Air passenger travel guide
- European Union / Your Europe: Air passenger rights
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Your route and travel date may change the answer. Check the linked official rule.